Atomic Mass
Atomic number
• The number of protons in the nucleus of the atom is equal to the atomic number (Z).
• Henry Moseley discovered the atomic number of each element using x-rays, which led to more accurate organization of the periodic table
Mass number of the atom
• Mass number of an atom is equal to the sum of the number of protons and neutrons in the nucleus.
• Dimitri Mendeleyev classified the elements according to their
chemical properties, he noticed patterns were in order with the mass number of the atom.
Atomic mass
• Mass of a neutron is 1.6749 10–27 kg
• Mass of a proton is 1.6726 10–27 kg
• Mass of an atom (mass number) is calculated as mass number = protons + neutrons
Atomic mass
• The unit of the atomic mass is «atomic mass unit» abbreviated as «u»
or «amu»
• 1 amu is also equal to 1 Dalton (Da)
Isotope
• Atoms that have the same atomic number (number of protons), but different mass numbers (number of protons and neutrons) are called isotopes.
6 proton + 6 neutron,
6 proton + 7 neutron
•
Mass spectrometry
• Mass spectrometry is used to determine the mass of an atom or molecule.
• Isotopes are separated through mass spectrometry. One can distinguish between isotopes of a given element by mass
spectrometry. A mass spectrometer separates each isotope by mass number
Mass spectrometry
•
• v2 = 2eV / m
• e / m = v / H.r
•
• Mathematical principle of mass spectrometry is given below:
Atomic spectroscopy
Serie a b
Lyman 1 2,3,4 …. UV
Balmer 2 3,4,5 …. Visible
Paschen 3 4,5,6 …. IR
Bracket 4 5,6,7 …. IR
Pfund 5 6,7,8 …. IR