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•  Gums are considered to be pathological

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(1)

GUMS

•  Gums and mucilage have similar

constitutions and on hydrolysis yield a mixture of sugars and uronic acids.

•  Gums are considered to be pathological

products, while mucilage is formed by

normal metabolism.

(2)

GUMS AND MUCILAGE

•  Gums are amorphous translucent

substances which are insoluble in alchohol and most organic solvents. It is soluble in water and gives a viscous, sticky

solutions.

•  Other gums are swollen by absorbing water to form a jelly –like mass.

•  Gums consist of Ca, Mg, and K salts of

polyuronides.

(3)

GUMS AND MUCILAGE

•  Gums can be hydrolysed by prolonged boiling with dilute acids to yield a mixture of sugars (mainly galactose, arabinose, xylose) and uronic acids.

•  Gums are commonly found in trees and

shrubs of a number of families such as

Leguminosae, Rosaceae, Sterculiaceae,

Rutaceae

(4)

Formation of Gums

§  Gums are abnormal products, formed by

injury of the plant unfavourable conditios (e.g.

drought)

§  By a breakdown of cell wals (a process of

extracellular formation called gummosis)

(5)

MUCILAGE

§  Mucilages are generally normal products of metabolism formed within the cell

(intracellular formation).

§  Fx of mucilages;

•  Storage material

•  Water storage reservoir

•  Protection for germinating seeds.

(6)

Occurence of mucilage

•  Mucilage is often found in;

•  Epidermal leaf cells (Senna)

•  Seeds coats (linseed, psyllium)

•  Roots (marshmallow)

•  Barks (Slippery elm)

(7)

Herbs containing gums

§  Gummi Arabicum-Acacia gum

§  Tracacantha gum

§  Gummi cerasi

(8)

Constituens of gums

•  A water soluble fraction (tragacanthine)

•  A water insoluble fraction (basorine)

•  Both these are insoluble in alcohol)

(9)

Acacia Gum, Gum Arabic (Arap zamkı)

•  Acacia gum is adried gum obtained from the stem and brances of Acacia senegal and

some other ssp of Acacia (Leguminosae).

•  Geographical sources: Kordofan, Senegal, Nigeria.

•  Some gum exudates from trees as a result

of the cracking of the bark, but most of the

best Kordofan is obtained from trees 6 years

old, tapped in February and March, or after

the rains when the leaves fall.

(10)

Acacia Gum, Gum Arabic (Arap zamkı)

•  A small axe is used to make a transverse incision in the bark. The axe is then twisted so that the bark is loosened. Strips are then pulled of above and below the cut. A portion of the cambium is then bared. This cambium then produces new phloem and in about 30 days the tears of gum which have formed on the surface may be picked off.

•  The gum is collected and then cleaned from

sand and vegetable debris and sorted.

(11)

Acacia Gum, Gum Arabic (Arap zamkı)

•  Kordofan gum is the best quality. It has few cracks on the surface or relatively

transparent.

•  Slightly pink-yellow in colour.

•  Tears are usually not very uniform in size (1-3 mm)

•  It is viscid and when diluted, does not

deposit on standing.

(12)

Acacia Gum, Gum Arabic (Arap zamkı)

•  Acacia is almost completely soluble in an equal weight of water (solution takes place rather slowly). This solution is slightly acidic and becomes more so on keeping,

especially if hot water is used to make the

solution.

(13)

Acacia Gum, Gum Arabic (Arap zamkı)

Constituents of Acacia;

§  Galactose

§  Arabinose

§  Rhamnose

§  Uronic acids

§  Oxydase enzymes On hydrolysis;

•  L-ramnozipyranose

•  D-galactopyranose

•  L-arabinose

(14)

Acacia Gum, Gum Arabic (Arap zamkı)

§  Uses of Acacia

§  Used as general stabilizer in emulsions, lozenges, granules, tablets, pats.

§  Demulsent properties used in coughs, sore throats.

§  It has a wide spread use in the food, drink, dye

and textile industries.

(15)

TRAGACANTHA (GUMMİ

TRAGACANTHAE) (TF) KİTRE ZAMKI

•  Tragacanth is the «air hardened gummy exudate flowing naturally or obtained by incision, from the trunk and brances of Astragalus gummifer and other ssp. of Astragalus.

•  Geographical sources of Tracacanth are;

Syria, Iraq, Iran and Russia.

(16)

TRAGACANTHA (GUMMİ

TRAGACANTHAE) (TF) KİTRE ZAMKI

§  Formation of Tragacanth

§  Tragacant is the gum that exudates

immediately after injury of the plant occurs and is therefore pre formed in the plant.

§  A section of a Tragacanth stem shows that the cell walls of the pith and medullary rays are

gradually transformed into gum (Gummosis).

(17)

TRAGACANTHA (GUMMİ

TRAGACANTHAE) (TF) KİTRE ZAMKI

Botanical sources of Tragacanth;

•  Astragalus gummifer,

•  A. microcephalus,

(18)

TRAGACANTHA (GUMMİ

TRAGACANTHAE) (TF) KİTRE ZAMKI

Methods of collection:

• The gum can be obtained from the plants in the 1st year . This is than of poor quality and unfit for

commercial use.

• Plants are normally tapped after the 2nd year. The earth is taken away from from the base to a depth of 5 cm. the exposed part is incised with a sharp knife and a wedge-pieces of wood is used the open the incision to exudate easilly. The wedge is left in the cut for up to 24 hours and the gum is collected for 2 days after incision.

(19)

TRAGACANTH (GUMMİ

TRAGACANTHAE) (TF) KİTRE ZAMKI

•  Grades of tragacanth;

•  Tragacanth is graded into several

qualities. The best grades form the official drug(Yaprak), while the lower grades are used in food, textile and other industries.

•  Tragacanth is an expensive commodity:

due to the scacity and extra treatments

andc tests needed to meet the microbial

requirements.

(20)

TRAGACANTH (GUMMİ TRAGACANTHAE) (TF) KİTRE ZAMKI

•  Yaprak tragacanth occurs in flattened ribbons. The surface shows number of ridges that indicates the temporary

stoppages of flow from the inclusion.

•  The gum is white or white-yellow in colour and translucent. It is odourless and has little test.

•  Tragacanth swells into a gelatinous mass

when placed in water but only a small

(21)

TRAGACANTH (GUMMİ TRAGACANTHAE) (TF) KİTRE ZAMKI

•  With strong iodine solutions, a previously soaked gum will turn a slight green colour, otherwise only a few blue spots will be

visible with a dilute solution of iodine.

(22)

TRAGACANTH (GUMMİ

TRAGACANTHAE) (TF) KİTRE ZAMKI

Constituents of Tragacanth

§  A water soluble fraction (tragacanthine)

§  A water insoluble fraction (basorine)

§  Both these are insoluble in alcohol)

§  Sugars

§  Uronic acids

§  Galacturonic acids, galactopyranose,

(23)

TRAGACANTH (GUMMİ

TRAGACANTHAE) (TF) KİTRE ZAMKI

Uses of Tragacanth

•  As a suspending agent for insoluble powders

•  Binding agent in pills and tablets

•  Additive for food industry.

(24)

Sterculia Gum (Karaya gum)

§  Sterculia gum is used to adulterate Tragacanth.

§  Sterculia gum is the gummy exudate obtained from the tree, Sterculia ssp.

§  Common names: Karaya gum, Indian Tragacanth, Bassora tragacanth

§  Geographical sources: India, Pakistan, Africa

§  This gum is official in BP

(25)

Gummi Ceraci

§  Gummi ceraci is a dried gum obtained from Prunus ssp. (sour cherry, cherry, peach,

apricot and plum).

§  Constituents of gum are glucuronic acids, galactopyranose, arabinose, xylose

§  Partly soluble in water.

§  Adhesive in industry.

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