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Soil Nutrients Testing using IR Photo Spectrometer

Shubham D. Hedaua, Rahul Nawkhareb, Dr.Pratik Hazarec, Ajay Tinguraid a PG Scholar, Electronics Engineering

a,b,c,d Waingangā College of Engineering & Management

ashubhamhedauu@gmail.com, brahulnawkhare26@gmail.com

Article History: Received: 11 January 2021; Revised: 12 February 2021; Accepted: 27 March 2021; Published online: 4 June 2021

Abstract: In India 70 of the general population economy clearly or by suggestion depending on the agricultural

association.which can be 15 - 20% of offers in the hard and fast Indian economy. it's a huge neighborhood a Green Nation India. in view of the shortfall of preparation and old advancement consistently a considerable number of farmers doing implosion in light of less productivity. Our Project's standard way to grow the productivity of the best piece of the general population to evolute the rural country into a made country.to make this dream of made country we need to examine to the cultivating territory for present-day propels. one of them we are finding the in all cases free structure to measure the soi supplements are N (Nitrogen), P (Phosphorus), K (Potassium) and show with their thought for farmers at their own lingos like Englis, Hindi, Marathi ( Regional Language Support) to better transparency of an enormous bit of the clueless social classes. with the help of this endeavor, we need to change the circumstance of developing in India. for this, we are developing the system from the above feature with its own power supply necessities fulfilled by Solar Energy and advanced lithium-molecule battery pack. we are developing the system in what course the soil testing technique is at present done in the exploration place by an answer/substance-based testing whose important 6 - 10 Hours of time are cleared out and our farmers can test its earth at its own site two or three minutes. while developing this system we are thing about to95% of accuracy over the lab

Keywords: Soil Nutrients, IR spectrophotometer,Precision Agriculture, DSP Processing. 1. Introduction

India Is an Agricultural country, thus we are compelling to an agrarian field while picking our task. while we study the current circumstance in the agrarian field we will track down a 60 - 75% of the Indian Economy is dependant on Farmers who are living in unassuming communities and towns. out of the most people groups are unskilled. large numbers of the public authority authorities and manures provider or the people groups experiences in this field they are taken benefits of the absence of lack of education of their clients which are the helpless ranchers. We can track down the main downside in our ranchers while they are developing their territories by deficient information on their areas soil and water quality that is the reason the profitability is extremely poor now and then it not may recuperate their put away cash for development and their actual endeavors. out of them, a few ranchers are taught henceforth they ought to follow the logical method of cultivating and get great outcomes. however, the cash and speculation are more in an ordinary method of soil testing procedure.Currently, soil testing is done in just the labs whose don't put close to ranchers, henceforth 90% of people groups can skirt this interaction and follows the regular method of the estate, treatment, and water supply.to make an Indian economy and GDP a lot more grounded we need to instructed or mindful our ranchers about how much soil wellbeing upkeep and improved by providing appropriate supplements to it. in the dirt there are numerous supplements are available out of this three principle significant supplements are N (Nitrogen), P (Phosphorus), K (Potassium), and other are optional supplements like a C (Calcium), S(Sulphur), M(Magnesium), C(Carbon), H(Hydrogen), O(Oxygen), and so forth Horticultural scientists are determined how to supply supplements in the dirt by straightforwardly forced or provided through the water.In this undertaking our mean to gauge every one of those supplements and show them on the screen to find satisfactory ways to keep up supplements in the dirt on the off chance that the dirt is solid, our croup likewise becomes sound and delivers huge creation to help the abundance of our ranchers. this why we are making an independent and simple to-utilize framework with the provincial language whose effectively open to peruse data to our ranchers. until we are doing an investigation on the most proficient method to quantify the supplements inside the dirt with no substance cycle collaboration which are effectively open runs with no consumable parts or fluid and zero support cost. while building up the framework above is the principle reason for the on the grounds that the people groups which are utilizing our framework they don't have effectively supply of required synthetic substances and support parts. from the examination, we have found another system that can be performed by as it were the Light source and photodiode called a Photospectrometer. in this interaction one of the light sources whose can 750-1500nm frequency passed from the under testing soil test, according to the supplements contains in the dirt it will mirror back the light beams at a specific frequency. as per radiation, we can indicate the rates of supplements that contain it.performing this

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additional advancement we can add an element wherein it showing the consequence of proposed supplements can supply from specific compost and its extent.

2. ExistingSystem

For crop streamlining and to shield the plant from ecological/Climate change issues soil testing is significant. By and large, for soil testing purposes, ranchers are encouraged to take soil tests to research facilities. A research facility soil test enjoys unequivocal benefits, yet it takes a more drawn out effort to sit tight for the test outcomes. Electrochemical Transducers are likewise utilized for checking soil supplements N, P, K. It utilizes particle specific anodes (ISE) and particle particular field-impact semiconductor (ISFET) for soil supplement discovery and is unequipped for constant detecting executions in view of the Slow Response in execution time. Electrochemical sensors are frequently more costly and bigger in size which makes them the most un-reasonable for the ranchers [3]. There are a few Sensors utilized in the current framework are Soil Moisture Sensors, Temperature Sensors, PH Value Sensors/Electrodes, Humidity Sensors, Color Sensors. these every one of the sensors are not appropriate for soil supplement testing in view of the distinction in perusing among regular and demonstrated compound testing results and electronic and electromechanical transducer-based frameworks. Henceforth we are making a framework that can eliminate the downside of the past framework with easy to understand and financially savvy to ranchers. there are some trying method utilized are as followed.

1:- Nutrients are sensed by using chemicals

As According to the Color of the arrangement is accustomed to investigating the supplement accessibility. Soil pH level Determination is generally estimated potentiometrically or pH test in a slurry utilizing an electronic pH meter. There are two terminals one is H+ delicate cathode and a reference anode are needed with mix anodes that contain the H+ touchy anode and the reference cathode is most regularly utilized.

2:- Electrical conductivity measurement

Electrical conductivity (EC) is the cycle where the capacity of material under testing conducts an electrical flow. The conductivity of soils shifts according to the number of water atoms present in soil particles. For this testing, we can utilize a dirt dampness sensor to quantify the conductivity of soil wasteful way. Another class of sensors estimates another property of dampness in soils called water potential. in a fig1 showing conductivity according to the property of the substance at the various levels.

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3. Proposed System

Fig 2. IR Spectrophotometer Working Pronciple

Spectrophotometry Spectrophotometry is a cycle used to gauge how much a compound substance (like N, P, K for our situation) ingests light by estimating the force of light as a light emission goes through an example arrangement or substance. The fundamental standard is that each compound ingests or mirrors light over a A specific scope of frequency (700 – 1500nm ). This Spectrophotometry can likewise be utilized to gauge the measure of a predefined synthetic substance. Spectrophotometry is quite possibly the most impressive and less tedious technique for quantitative examination in different fields, for example, Chemistry, Physics, Biochemistry, Material Science, Chemical Engineering, and Clinical applications Hence we are utilized it testing the soil with no compound cycle collaboration. An IR spectrophotometer is an insightful instrumentation sensor used to recognize materials including natural polymers like N, P, K. FT Fourier changes IR spectrometers can be utilized in an assortment of enterprises and cultivating including ecological, agrarian drug, and petrochemical. There is two numerical hypotheses are utilized as followed for the above technique.ATR - Attenuated total reflectance&FT-IR - Fourier transform infrared

ATR ( Attenuated all out reflectance ) is quite possibly the main cycle utilized for examining methods in the cutting edge time. At the point when an Infra-Red (IR) Light pillar goes from a medium like any substance of high refractive list (for example zinc selenide gem) to a mechanism of low refractive file test under testing, some measure of the light is reflected once again into the low refractive list medium. At the specific point of frequency, practically the entirety of the light waves is reflected back wonder is called absolute interior reflection.

FTIR ( Fourier change infrared spectroscopy ) is the numerical cycle of Fourier change to deciphering the crude information from range frequency interferogram into the real range frequency. Fourier change infrared spectroscopy technique is utilized to acquire the infrared range of transmission or ingestion of fuel or soil test under testing. photograph spectrometer and FTIR distinguish the presence of natural and inorganic mixtures in the example under testing. Contingent upon the IR.is a method used to get an infrared range of assimilation or emanation of a strong, fluid or gas. high-goal unearthly information over a wide phantom reach. This presents a critical benefit over a dispersive spectrometer, which estimates force over a thin scope of frequencies all at once.

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4. BlockDiagram

Fig 3. Block Diagram of our proposed system

The primary objective is to incorporate a detecting module with an Image handling set up to screen the fundamental subtleties required for plant development from the dirt.The proposed framework has 3 primary modules

a)

Sensingmodule

b)

Communication module

c)

Determining By ItWavelength

d)

Battery & SolarPannel

e)

EEPROM

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It delivers the ideal scope of frequency of light. At first, a light source (IR) falls onto a focal point (collimator) whose packed light into straight light emission (light) to sends that goes through a crystal (monochromator) to part it into a few segment spectra ( frequencies). At that point, a frequency cut (selector) communicates just the ideal frequencies, as demonstrated in Figure 1. Photometer:- Transmitted wanted to reach (frequency) of light passes from the testing arrangement of an example in a cuvette, the Photodiode (photometer) recognizes the number of photons focused on its, that is retained and afterward conveys a message to a galvanometer or a computerized Signal Processor, as represented in Figure 2. The AS7265x (Make - SparkFun) Triad Spectroscopy Sensor is an amazing optical sensor otherwise called a spectrophotometer [4]. There AS7265x ghastly sensors are accessible with an alternate classification of light sources like a the noticeable light source, UV, and IR LEDs to enlighten and test different surfaces for light spectroscopy. The spectrophotometer is comprised of three sensors; the AS72651, the AS72652, and the AS72653 and can distinguish light from 410nm (UV) to 940nm (IR). Additionally, 18 individual light source frequencies can be estimated with exactness down to 28.6 nW/cm2 and a precision of 12%. The SparkFun AS7265x Spectroscopy Sensor speaks with DSP Processor over IIC as a matter of course or over Baud Rate 115200bps sequential. The Sensor can be set up utilizing AT Commands to impart over sequential.

Spectrophotometry Working Principle :-Spectrophotometry is a part of electromagnetic spectroscopy worried about the quantitative estimation of the reflection or transmission properties of a material as an element of frequency. Spectrophotometry utilizes photometers, known as spectrophotometers, that can gauge the power of a light bar at various frequencies. In spite of the fact that spectrophotometry is most normally applied to bright, apparent, and infrared radiation, present day spectrophotometers can examine wide areas of the electromagnetic range, including x-beam, bright, noticeable, infrared, and additionally microwave frequencies.

Overview of Spectrophotometry :-Spectrophotometry is a device that relies on the quantitative investigation of particles relying upon how much light is consumed by shaded mixtures. Significant highlights of spectrophotometers are ghastly transfer speed (the scope of tones it can send through the test), the level of test transmission, the logarithmic scope of test ingestion, and now and again a level of reflectance estimation.A spectrophotometer is normally utilized for the estimation of conveyance or reflectance of arrangements, straightforward or obscure solids, like cleaned glass, or gases. Albeit numerous biochemicals are shaded, as in, they retain noticeable light and hence can be estimated by colorimetric strategies, even lackluster biochemicals can regularly be changed over to hued compounds appropriate for chromogenic shading framing responses to yield compounds reasonable for colorimetric analysis. However, they can likewise be intended to gauge the diffusivity on any of the recorded light ranges that normally cover around 200 nm - 2500 nm utilizing various controls and calibrations.Within these scopes of light, alignments are required on the machine utilizing principles that fluctuate in type contingent upon the frequency of the photometric determination. An illustration of an investigation in which spectrophotometry is utilized is the assurance of the balance steady of an answer. A specific compound response inside an answer may happen in a forward and turn around course, where reactants structure items and items separate into reactants. Eventually, this compound response will arrive at a state of equilibrium called a harmony point. To decide the individual convergences of reactants and items now, the light conveyance of the arrangement can be tried utilizing spectrophotometry. The measure of light that goes through the arrangement is characteristic of the convergence of specific synthetic compounds that don't permit light to go through.The retention of light is because of the cooperation of light with the electronic and vibrational methods of particles. Each sort of particle has an individual arrangement of energy levels related with the cosmetics of its synthetic bonds and cores and hence will retain light of explicit frequencies, or energies, bringing about interesting otherworldly properties. This depends on its particular and unmistakable cosmetics. The utilization of spectrophotometers traverses different logical fields, like physical science, materials science, science, organic chemistry, Chemical Engineering, and sub-atomic biology. They are generally utilized in numerous ventures including semiconductors, laser and optical assembling, printing, and criminological assessment, also in research centers for the investigation of synthetic substances. Spectrophotometry is regularly utilized in estimations of chemical exercises, conclusions of protein fixations, judgments of enzymatic dynamic constants, and estimations of ligand restricting reactions. Ultimately, a spectrophotometer can decide, contingent upon the control or adjustment, what substances are available in an objective and precisely how much through computations of noticed frequencies. In cosmology, the term spectrophotometry alludes to the estimation of the range of a divine article wherein the motion size of the range is aligned as an element of frequency, for the most part by correlation with a perception of a spectrophotometric standard star, and revised for the retention of light by the Earth's environment.

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History :- Planned by Arnold O. Beckman in 1940[disputed–discuss],the spectrophotometer was made with the guide of his partners at his association National Technical Laboratories set up in 1935 which would become Beckman Instrument Company and in the end Beckman Coulter. This would come as a response for the as of late made spectrophotometers which couldn't ingest the splendid viably. He would start with the development of Model A where a glass precious stone was used to acclimatize the UV light. It would be found that this didn't give great results, consequently in Model B, there was a shift from a glass to a quartz precious stone which contemplated better absorbance results. Starting there, Model C was carried into the world with an acclimation to the recurrence objective which ended up having three units of it conveyed. The last and most standard model became Model D which is better seen now as the DU spectrophotometer which contained the instrument case, hydrogen light with ultraviolent continuum, and a better monochromator.It was made from 1941 than 1976 where the expense for it in 1941 was US$723 (far-UV lace were an option to additional detriment). In the outflows of Nobel science laureate Bruce Merrifield, it was "likely the primary instrument anytime made towards the movement of bioscience."

At the point when it got suspended in 1976, Hewlett-Packard made the primary mechanically available diode-display spectrophotometer in 1979 known as the HP 8450A. Diode-display spectrophotometers differentiated from the principal spectrophotometer made by Beckman because it was the essential single-bar central processor controlled spectrophotometer that checked various frequencies at the same time very soon. It enlightens the model with polychromatic light which the model absorbs depending upon its properties. By then it is sent back by granulating the photodiode show which recognizes the recurrence space of the reach. From here on out, the creation and execution of spectrophotometry contraptions has extended colossally and has gotten perhaps the most inventive instruments inside ongoing memory.

Design Plan :- Single bar looking at spectrophotometer There are two critical classes of contraptions: single bar and twofold shaft. A twofold shaft spectrophotometer[13] takes a gander at the light force between two light ways, one way containing a reference test and the other the test. A singular shaft spectrophotometer assesses the overall light power of the column when a test is installed. Regardless of the way that connection assessments from twofold bar instruments are less difficult and all the more consistent, single-column instruments can have a greater interesting reach and are optically not so much troublesome but rather more decreased. Likewise, some specific instruments, for instance, spectrophotometers manufactured onto amplifying focal point or telescopes, are single-bar instruments as a result of sensibility. Obviously, spectrophotometers use a monochromator containing a diffraction crushing to make the sensible reach. The pounding can either be versatile or fixed. If a singular locater, for instance, a photomultiplier chamber or photodiode is used, the pounding can be sifted stepwise (looking at spectrophotometer) so the identifier can measure the light power at each recurrence (which will contrast with every "movement"). Assortments of finders (bunch spectrophotometer, for instance, charge coupled devices (CCD) or photodiode shows (PDA) can in like manner be used. In such structures, the pounding is fixed and the force of each recurrence of light is assessed by a substitute finder in the show. Additionally, most current mid-infrared spectrophotometers use a Fourier change methodology to get the apparition information. This system is called Fourier change infrared spectroscopy. When making transmission assessments, the spectrophotometer quantitatively ponders the unimportant segment of light that goes through a reference course of action and a test plan, by then electronically takes a gander at the powers of the two signals and registers the degree of transmission of the model appeared differently in relation to the reference standard. For reflectance assessments, the spectrophotometer quantitatively dissects the little segment of light that reflects from the reference and test tests. Light from the source light is gone through a monochromator, which diffracts the light into a "rainbow" of frequencies through a turning gem and yields slim exchange paces of this diffracted range through a mechanical cut on the yield side of the monochromator. These exchange speeds are conveyed through the test. By then the photon progress thickness (watts per meter squared usually) of the imparted or reflected light is assessed with a photodiode, charge coupled contraption or other light sensor. The transport or reflectance a motivator for each recurrence of the test is then differentiated and the transmission or reflectance regards from the reference test. Most instruments will apply a logarithmic ability to the immediate movement extent to figure the 'responsiveness' of the model, a value which is relating to the 'centralization' of the manufactured being assessed.

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Fig 5.Design Setup of Photospectrometer

To lay it out simply, the gathering of events in a looking at spectrophotometer is according to the accompanying:

1.The light source is shone into a monochromator, diffracted into a rainbow, and split into two shafts. It is then investigated the model and the reference game plans.

2.Fractions of the event frequencies are conveyed through, or reflected from, the model and the reference. 3.The resultant light strikes the photodetector contraption, which takes a gander at the general power of the two bars.

4.Electronic circuits convert the overall streams into straight transmission rates just as absorbance/obsession regards.

In a bunch spectrophotometer, the progression is as per the following: 1.The light source is shone into the model and focused into a cut 2.The sent light is refracted into a rainbow with the reflection pounding

3.The coming about light strikes the photodetector contraption which takes a gander at the force of the column 4.Electronic circuits convert the general streams into direct transmission rates just as absorbance/center regards Various more prepared spectrophotometers ought to be changed by a technique known as "centering", to change the invalid energy yield of the two columns at the locater. The transmission of a reference substance is set as an example (datum) regard, so the transmission of any excess substances is recorded nearly with the hidden "centered" substance. The spectrophotometer by then changes over the transmission extent into 'retentiveness', the intermingling of express portions of the test near with the fundamental substance.

6. Software Used

Proteus 8.3 Professional :-The Proteus Design Suite is a restrictive programming device suite utilized fundamentally for electronic plan computerization. The product is utilized for the most part by electronic plan architects and professionals to make schematics and electronic prints for assembling printed circuit sheets.

Arduino1.8.3 :-The Arduino Integrated Development Environment - or Arduino Software (IDE) - contains a substance administrator for creating code, a message an area, a book solace, a toolbar with gets for typical limits and a movement of menus. It interfaces with the Arduino and Genuino gear to move programs and talk with them. Making Sketches :-Activities formed using Arduino Software (IDE) are called traces. These portrayals are written in the substance supervisor and are saved with the record development .ino. The chief has features for cutting/staying and for looking/overriding content. The message an area gives analysis while saving and conveying and moreover shows botches. The solace shows text yield by the Arduino Software (IDE), including absolute error messages and other information. The base righthand corner of the window shows the masterminded board and consecutive port. The toolbar gets grant you to affirm and move programs, make, open, and save depicts.

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Express PCB V2.0 :- There are two sections to ExpressPCB, our CAD programming and our board fabricating administration. Our Computer aided design programming incorporates ExpressSCH for drawing schematics and ExpressPCB for planning circuitsheets. After you complete your PC board plan, we give an ease, top caliber and quick hotspot for having your sheets made. Here is the manner by which it works:

1. We suggest that you start your undertaking by drawing a schematic utilizing ExpressSCH. Drawing a schematic isn't needed, yet it will save you time when planning your load up what's more, lessen the chance of wiring blunders.

2. Then, utilize the ExpressPCB program to format your PC board. In the event that you connect your schematic to ExpressPCB, the program will direct you through the wiring interaction by featuring how the parts ought to be associated.

3. At the point when your format is finished, you can decide the specific expense of having your sheets made with the Compute Board Cost order.

7. Results And Discussion

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This task proposed a dirt picture design order to recognize NPK with a mix of surface and shading highlight extraction. Pictures are characterized by help vector machine classifier. A mix of a few highlights is utilized to assess the suitable highlights to discover particular highlights for distinguishing proof of soil NPK. Likewise the ecological Factors for example Dampness, temperature/moistness, pH esteems from sensors are likewise refreshed to the rancher.

8. Future Scope

Upgrade the aftereffect of NPK proportion to NPK amount location.

• Building a portable application which interconnects every one of the ranchers and incorporates every one of the subtleties required about plant development and Marketing of types of gear and composts.

• Use of WSN. 9. Conclusion

Results show that the immediate measurement of nitrogen, phosphorus and potassium (NPK) in composts utilizing UV-Vis spectroscopy is just practical if impedance modes between all examples are thought of. We showed that the utilization of groups for the measurement of nitrogen with straight or logarithmic relapse models doesn't create logical evaluation adjustments. Moreover, multivariate relapse models that can consider examples obstruction perform ineffectively for lower absorbance supplements like P and K. Regardless of the data about P and K being available in the spectra, PLS-R models can't adapt to all the current co-change modes, delivering a middle inert factors projection model that has critical connection however high difference. The high impedance of phosphorus in the spectra has demonstrated to be tackled by oneself learning AI calculation. Results demonstrate that once co-change modes are found and the impedances are accurately represented in the forecast models, measurement accomplishes insightful evaluation quality. This controlled test will be tried with Micro-Irrigation Systems toward the advancement of a scientific evaluation NPK checking dependent on UV-Vis spectroscopy and man-made consciousness.

References

1. Sabina Rahaman, Harshitha M, Anusha R, Bhargavi YR, Chandana M “ Detection of NPK Ratio Level Using SVM Algorithm And Smart Agro Sensor System ” International Journal of Latest Research in Engineering and Technology (IJLRET) ISSN: 2454-5031 Volume 03.

2. A.Niranjan1, S.N.V.SaiMukhesh, KondaAnudeep Reddy, M. Surya Pratap “ Soil Nutrient Tester ” International Journal of Engineering Technology Science and Research Volume 5, Issue 4.

3. Filipe Monteiro-Silva, Pedro A. S. Jorge, Rui C. Martins “ Optical Sensing of Nitrogen, Phosphorus and Potassium: A Spectrophotometrical Approach toward Smart Nutrient Deployment ” Centre for Applied Photonics, INESC TEC, Faculty of Sciences of the University of Porto, Rua do CampoAlegre, s/n, 4169-007 Porto, Portugal.

4. Arun Kumar, Abhishek Kumar, Akash De, ShashankShekhar, Rohan Kumar Singh “ IoT Based Farming Recommendation System Using Soil Nutrient and Environmental Condition Detection ” International Journal of Innovative Technology and Exploring Engineering (IJITEE) ISSN: 2278-3075, Volume-8 Issue-11.

5. Sonikajha ,Suneetha V “Nutrient analysis of soil samples from various places ” Journal of Chemical and Pharmaceutical Research, 2015, 7(3): 291-293

6. Kerkhoff AJ, Fagan WF, Elser JJ, Enquist BJ “ American Naturalist ” 168: E103–E122.

7. Subramani S., Kannaiyan S. “ Effect of the water fern Azolla on enzyme activity in soil under rice 8. cultivation. Mikrobiologia”

9. Meyer, D., J.P. Harner, E.E. Tooman, C. Collar.“ Evaluation of weeping wall efficiency of solid liquid separation. Applied Engineering in Agriculture ”

10. Food and Agriculture Organization of the United Nations. World Fertilizer Trends and Outlook to 2018; FAO:Rome, Italy, 2015.

11. Magen, H. Fertigation: An overview of some practical aspects. In Fertilizer News; The ertilizerAssociationof India: New Delhi, India, 1995.

12. Markets, R. Liquid Fertilizer Market: Global Industry Analysis, Trends, Market Size & Forecasts to 2023.

13. Noori, O.; Panda, S.S. Site-specific management of common olive: Remote sensing, geospatial, and advancedimage processing applications. Comput.Electron. Agric. 2016, 127, 680–689

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