EK-2k:
MSDS
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1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name : Chemosil X 6070 - 25kg - IDH 3016647
1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the
Sub-stance/Mixture
: Binder , solvent-based
1.3 Details of the supplier of the safety data sheet
Company : LEHVOSS UK Limited
2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008)
Flammable liquids, Category 2 H225: Highly flammable liquid and vapour . Skin irritation, Category 2 H315: Causes skin irritation.
Reproductive toxicity , Category 2 H361d: Suspected of damaging the unborn child.
Specific target organ toxicity - repeated exposure, Category 2
H373: May cause damage to organs through pro-longed or repeated exposure.
Acute toxicity , Category 4 H332: Harmful if inhaled.
H312: Harmful in contact with skin.
Classification (67/548/EEC, 1999/45/EC)
Flammable R10: Flammable.
Harmful R48/20: Harmful: danger of serious damage to
health by prolonged exposure through inhalation.
R20/21: Harmful by inhalation and in contact with skin.
T oxic to Reproduction Category 3 R63: Possible risk of harm to the unborn child.
Irritant R38: Irritating to skin.
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2 / 12 2.2 Label elements
Labelling (REGULA TION (EC) No 1272/2008) Hazard pictograms :
Signal word : Danger
Hazard statements : H225 Highly flammable liquid and vapour . H315 Causes skin irritation.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs through pro-longed or repeated exposure.
H312 Harmful in contact with skin.
H332 Harmful if inhaled.
Precautionary statements : Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P243 T ake precautionary measures against static discharge.
P260 Do not breathe dust/ fume/ gas/ mist/ va-pours/ spray .
P280 Wear protective gloves/ protective clothing/
eye protection/ face protection.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ T ake off immediately all contaminated clothing.
Rinse skin with water/ shower.
P308 + P313 IF exposed or concerned: Get medical ad-vice/ attention.
P331 Do NOT induce vomiting.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
Hazardous components which must be listed on the label:
108-88-3 toluene
Labelling according to EC Directives (1999/45/EC) Hazard pictograms :
R-phrase(s) : R10 Flammable.
R38 Irritating to skin.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through
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halation.
R63 Possible risk of harm to the unborn child.
R65 Harmful: may cause lung damage if swal-lowed.
S-phrase(s) : S36/37 Wear suitable protective clothing and gloves.
S43 In case of fire, use sand, dry chemical or alcohol-resistant foam.
S60 This material and its container must be disposed of as hazardous waste.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
Hazardous components which must be listed on the label:
1330-20-7 xylene
For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.
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4 / 12 4. First aid measures
4.1 Description of first aid measures
General advice : Victim to lie down in the recovery position, cover and keep him warm.
T ake off all contaminated clothing immediately .
If inhaled : Remove to fresh air.
If symptoms persist, call a physician.
In case of skin contact : Wash off immediately with soap and plenty of water . Burns must be treated by a physician.
In case of eye contact : Rinse thoroughly with plenty of water , also under the eyelids.
If symptoms persist, call a physician.
If swallowed : Clean mouth with water and drink afterwards plenty of water . Call a physician immediately .
Do NOT induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
4.3 Indication of any immediate medical attention and special treatment needed
5. Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media : Use water spray , alcohol-resistant foam, dry chemical or car-bon dioxide.
Water spray jet
Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment.
Unsuitable extinguishing media
: High volume water jet
5.2 Special hazards arising from the substance or mixture 5.3 Advice for firefighters
Special protective equipment for firefighters
: In the event of fire, wear self-contained breathing apparatus.
Further information : Cool endangered containers with water spray jet.
6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Avoid contact with skin, eyes and clothing.
Avoid inhalation of vapour or mist.
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Wear personal protective equipment.
6.2 Environmental precautions
Environmental precautions : Do not allow contact with soil, surface or ground water.
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder , sawdust).
Dispose of in accordance with local regulations.
Ensure adequate ventilation.
Do not flush with water or aqueous cleaning agents.
6.4 Reference to other sections
7. Handling and storage
7.1 Precautions for safe handling
Advice on safe handling : Ensure good ventilation at machinery Keep container tightly closed.
Provide sufficient air exchange and/or exhaust in work rooms.
Avoid formation of aerosol.
Avoid contact with skin and eyes.
Smoking, eating and drinking should be prohibited in the ap-plication area.
Advice on protection against fire and explosion
: Keep away from heat and sources of ignition.
T ake measures to prevent the build up of electrostatic charge.
7.2 Conditions for safe storage, including any incompatibilities Requirements for storage
areas and containers
: Keep tightly closed in a dry , cool and well-ventilated place.
Store in original container.
Storage rooms must comply with the technical regulations for flammable liquids (flammable liquids).
Advice on common storage : Do not store together with oxidizing and self-igniting products.
German storage class : 3 Flammable liquids 7.3 Specific end uses
8. Exposure controls/personal protection 8.1 Control parameters
Components CAS-No. V alue Control
pa-rameters Update Basis
xylene 1330-20-7 TWA 50 ppm
220 mg/m3
2005-04-06 GB EH40
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6 / 12 Further
infor-mation
: Sk: Can be absorbed through skin. The assigned substances are tho se for w hich there are concerns that dermal absorptio n w ill lea d to systemic toxicity .
STEL 100 ppm 441 mg/m3
2005-04-06 GB EH40
Further infor-mation
: Sk: Can be absorbed through skin. The assigned substances are tho se for w hich there are concerns that dermal absorptio n w ill lea d to systemic toxicity .
TWA 50 ppm
221 mg/m3
2000-06-16 2000/39/EC
Further infor-mation
: skin: Identifies the possibility of significant uptake through the skin Indicative
: skin: Identifies the possibility of significant uptake through the skin Indicative
: skin: Identifies the possibility of significant uptake through the skin Indicative
: skin: Identifies the possibility of significant uptake through the skin Indicative
: Sk: Can be absorbed through skin. The assigned substances are tho se for w hich there are concerns that dermal absorptio n w ill lea d to systemic toxicity .
STEL 125 ppm 552 mg/m3
2005-04-06 GB EH40
Further infor-mation
: Sk: Can be absorbed through skin. The assigned substances are tho se for w hich there are concerns that dermal absorptio n w ill lea d to systemic toxicity .
toluene 108-88-3 TWA 50 ppm
192 mg/m3
2006-02-09 2006/15/EC
Further infor- : skin: Identifies the possibility of significant uptake through the skin
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: skin: Identifies the possibility of significant uptake through the skin Indicative
: Sk: Can be absorbed through skin. The assigned substances are tho se for w hich there are concerns that dermal absorptio n w ill lea d to systemic toxicity .
STEL 100 ppm 384 mg/m3
2007-08-01 GB EH40
Further infor-mation
: Sk: Can be absorbed through skin. The assigned substances are tho se for w hich there are concerns that dermal absorptio n w ill lea d to systemic toxicity .
Carbon black 1333-86-4 TWA 3,5 mg/m3 2005-04-06 GB EH40
STEL 7 mg/m3 2005-04-06 GB EH40
8.2 Exposure controls Engineering measures
Effective exhaust ventilation system Personal protective equipment
Respiratory protection : Breathing apparatus with filter . filter A2
Self-contained breathing apparatus (EN 133) Hand protection : Protective gloves
The suitability for a specific workplace should be discussed with the producers of the protective gloves.
The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other .
As the product is a mixture of several substances, the durabil-ity of the glove materials cannot be calculated in advance and has to be tested before use.
The exact break through time can be obtained from the pro-tective glove producer and this has to be observed.
The break through time depends amongst other things on the material, the thickness and the type of glove and therefore has to be measured for each case.
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Request information on glove permeation properties from the glove supplier .
Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work.
Eye protection : Tightly fitting safety goggles Skin and body protection : Wear suitable protective clothing.
Protective measures : Keep away from food, drink and animal feedingstuffs.
Remove soiled or soaked clothing immediately . Wash thoroughly after handling.
Avoid contact with the skin and the eyes.
Environmental exposure controls
General advice : Do not allow contact with soil, surface or ground water.
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance : liquid
Colour : black
Odour : solvent-like
Flash point : 22 °C
Lower explosion limit : This product is not explosive at itsself, but it may form explo-sive aerosol.
Boiling point/boiling range : > 110 °C
Density : 0,89 - 0,93 g/cm3
at 20 °C Water solubility : insoluble Viscosity , dynamic : 300 - 700 mPa.s
at 25 °C
Viscosity , kinematic : no data available 9.2 Other information
10. Stability and reactivity 10.1Reactivity
10.2Chemical stability
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9 / 12 No decomposition if stored and applied as directed.
10.3Possibility of hazardous reactions
Hazardous reactions : None known.
10.4Conditions to avoid
Conditions to avoid : no data available 10.5Incompatible materials
Materials to avoid : no data available 10.6Hazardous decomposition products
Hazardous decomposition products
: Carbon monoxide, carbon dioxide and unburned hydrocar-bons (smoke).
1 1. T oxicological information
11.1 Information on toxicological effects Acute toxicity
Acute oral toxicity
xylene : LD50 Oral: 8.700 mg/kg
Species: rat
Skin irritation : Irritating to skin and mucous membranes
Prolonged skin contact may cause skin irritation and/or der-matitis.
Serious eye damage/eye irritation
Eye irritation : Eye irritation Respiratory or skin sensitization
Sensitisation
xylene : No known sensitising effect.
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12.5 Results of PBT and vPvB assessment
This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
12.6 Other adverse effects Additional ecological infor-mation
: The product should not be allowed to enter drains, water courses or the soil.
13. Disposal considerations
13.1 Waste treatment methods
Product : Dispose of in accordance with the European Directives on waste and hazardous waste.
In accordance with local and national regulations.
According to the European Waste Catalogue, Waste Codes are not product specific, but application specific.
Contaminated packaging : Dispose of in accordance with local regulations.
Dispose of as unused product.
14. T ransport information
ADR
UN number : 1 133
UN proper shipping name : ADHESIVES Transport hazard class(es) : 3
Packing group : II
Classification Code : F1
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1 1 / 12 Hazard identification No : 33
Labels : 3
Tunnel restriction code : (D/E) Environmentally hazardous : no IAT A
UN number : 1 133
Description of the goods : Adhesives
Class : 3
Description of the goods : ADHESIVES
Class : 3
Description of the goods : ADHESIVES Transport hazard class(es) : 3
Packing group : II
Classification Code : F1 Hazard identification No : 33
Labels : 3
Environmentally hazardous : no
15. Regulatory information
15.1 Safety , health and environmental regulations/legislation specific for the substance or mixture
Other regulations : The product is classified and labelled in accordance with EC directives or respective national laws.
15.2 Chemical Safety Assessment
A Chemical Safety Assessment has not been carried out
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12 / 12 16. Other information
Full text of R-phrases referred to under sections 2 and 3
R10 Flammable.
R1 1 Highly flammable.
R20 Harmful by inhalation.
R20/21 Harmful by inhalation and in contact with skin.
R38 Irritating to skin.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R63 Possible risk of harm to the unborn child.
R65 Harmful: may cause lung damage if swallowed.
R67 V apours may cause drowsiness and dizziness.
Full text of H-Statements referred to under sections 2 and 3.
H225 Highly flammable liquid and vapour . H226 Flammable liquid and vapour .
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H332 Harmful if inhaled.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
Further information
Contact Point : LEHVOSS UK
The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-mation and belief at the date of its publication. The inforinfor-mation given is designed only as a guid-ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific mate-rial designated and may not be valid for such matemate-rial used in combination with any other materi-als or in any process, unless specified in the text.
This safety datasheet only contains information relating to safety and does not replace any prod-uct information or prodprod-uct specification.