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Electrochemistry is involved in the transport of electrons in

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(1)

Electrochemistry is involved in the transport of electrons in

matter, the conversion of electrical energy into chemical

energy, and the conversion of chemical energy into electrical

energy. It deals with events that both use electricity and

generate electricity. Electrochemistry also forms the basis of

oxidation - reduction reactions based on electron exchange.

(2)

There are two types of electrical conductivity.

• Metallic conductivity (electronic conductivity): Electrons and the current is carried in one direction. Electrons must be taken from the other side to provide current.

• Electrolytic conductivity: It is the conductivity seen in the solutions

and the transport of the current is through the + and - charged ions

in the solution. Current is also transported in two direction. This

conductivity increases with temperature and concentration. This

conductivity is also related to the transport of ions through ions.

(3)

A full electronic circuit is required to obtain an electric

current. If an electrolytic conductive compound is placed

between this closed circuit, chemical reactions take place

on the electrodes. As a result, the electric energy is used

to bring about a chemical change. This is called

electrolysis. Electrolysis cell is described as a mechanism

that converts electrical energy into chemical energy.

(4)
(5)

Oxidation is electron loss, and reduction is electron gain. ANION to the moving ions towards the anode, CATION to the ions moving towards the cathode.

The electrode that is oxidized is called the anode.

The electrode that is reduced is called the cathode.

(6)

 

Faraday’s law is divided into two basic laws

• The change of an electric current or the amount of reduced and oxidized matter in the interfaces is directly proportional to the amount of electricity passing through the solution.

Quantity of matter = amount of electricity = current intensity x Time;

w = Q = I x t.

The unit of Q is Kulon, the unit of I is Amper and the unit of time (t) is

• The amounts of the various substances that reduced and

oxidized in the interfaces with the same amount of electricity,

are proportional to equivalent weights.

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