renge kadar titre edilir.

(1)

213 1

! " #$ # % # & #

' () * + + ,- + . ,

#/ 0 1 2 3 3 4 0 0 5

6 3 #

Ayar

⁺ ^. ^,

1- 105

^o⁷ ⁸ ⁰ ⁹ ⁵ ⁵ ⁵ ⁵ ^: ⁰ ^; ^< ⁼ ⁰ ⁶ ⁵ ^> ⁼ ^? ^; ^/

= 6 3 @ 3 3 3 # A B 9 6 3 9 9 @ = = 9 0

9 5 3 3: C / 0 0 5 D D E 2 ; = ; 0 4

edilir ve 0.5 N sodyum hidro

⁹ ⁰ ⁰ ⁹ ⁶ ^@ ⁼ ⁶ ⁰ ⁼ ⁵ ⁹ ^< ^@

renge kadar titre edilir.

#/ 0 F F 2 # G = 0 6 5 > = ? ;

: H #

2-

^I ⁼ ⁶ ⁵ ^> ⁼ ⁹ ⁰ ⁰ ⁶ ⁰ ³ ⁶ ³ ^> ⁼ ⁹ ⁼ ⁹

0 0 9 5 3 @ # J 5 5 2 / # 0 = 6 5 > = 9 0

0 E ; = ; 9 : 30 3 #/ > = 9 = 9 0 0

E 9 0 6 = 5 @ : = 9 0 3 ; = ; K 9 9

i rengi

9 6 @ = B 9 3 #

3.3.2 Antipirin (Fenazon) Miktar Tayini

N N O H

₃

C

H

₃

C

M.A.=188

1-fenil-2,3-dimetil-5-pirazolon

B 4 3 3 3: E L M !5 9 0 = 6 5

0 D D # J 6 B N 3 9 5 4 4 D 9 9 0

le reaksiyonun geri

(2)

214

D : D # / # N

2

0 4 4 0 39 0 39 9 6 9

2 9 9 9 39 @ 6 @ 9 # / 7 7

4

4 9 9

D 0 0 39 0 39 9 3 # O6 = 5 ; 0 3 #

2

S

2

O

3

0

# P 9 0 6 = 5 @ : = 9 0 3 7 7

4

@ 9 0 3 9 < @

9 6 @ = 0 3 0 < 3 #

1 ml 0.1 N I

₂^F ^F ^F ^F ^F ^F ^F ^F ^F ^F ^# ^Q ^# ² ^; ⁼ ^: ^H ^#

(15 x f I

2

) - (b x f Na

2

S

2

O

3

& F F F F F F $

^$ ^R ^S ³ ^% ^M ^; ⁼

Reaksiyon denklemi:

T U V W V . - W X Y + ,

lan Ayarl

^, ^-

: 0.1N I

2

, 0.1N Na

2

S

2

O

3

0.1N I

2

+ + ,- + . , Z [ U - + . ,

! 2 #\ Q 6 = # ! # 8 6 = E 8 ] N 4

0 5 9 3: 33 9 D D 4 0 5 !6 3 #

[ - + - V ^ _ ^ - ` , U - + . ,

#2 B 4 3 6 B 9 5 5 5 5 : $ 0

2

O

3

! @ 3

3 3 # 2 M 2 ! 9 0 30 33 9 D D # a 6 0 5

4 #2 = ? 33 # P 9 0 < 0 B 6 9 6

0 3 9 3 3 36 D B 6 9 D 7 4 # b > 0 =

nra asit,

(3)

215 NaHCO

3

: # c 0 6 = 0 0 3 = 5 : @ B 9 N 0

9 6 3; 9 =

2

CO

3

! 2 > 4 # J 6 B

> 3 3: = < 0 5 5 E # N

2

0

re edilir.

d 9 4 = 9 0 3 3 0 < 0 3 : 0 0 9 = 5 < 4

renge kadar titrasyona devam edilir.

1 ml 0.1N I

₂^F ^F ^F ^F ^F ^F ^F ^F ^# ^Q ^\ ^$ ⁰ ₂

O

₃^! ^: ^H ^#

Reaksiyon denklemi:

0.1N Na

2

S

2

O

3

⁺ ⁺ ^,^- ⁺ ^. ^, ^Z ^[

U - + . ,

Na

2

S

2

O

3

. 5H

2

O: 248.19

! 2 #L 2 0 ; # ! #

26 g Na

2

S

2

O

3

ve 200 mg Na

2

CO

3

E 6 9 6 33< 0 = H 5 5 5 : 0

0 5 D D 4 !6 3 #

$ 6 6 = 0 D ; 6 = 5 6 = 0 3 9

9 0 6 = 6 33 # J 5 0 @ < 0 = 9 6 = 4 6

0 ] N ! 6 = 3H 39 @ 3 E A # G = 0 6 5

iyodat, potasyum bromat, potasyu

^@ ⁹ ⁼ ^E ^@ ⁹ ³ ⁹ ⁵ ³ ^@ ^#

e 6 5 6 = 6 = 0 D ; @ @ B 9 5 3H 3 3

E B 6 = 0 ; 9 D 6 # b > 0 = @ 5 0

= 9 9 5 33< 6 = 0 D ; 3 ; 9 D 0 < 3 # J 5 5 E ; 9 D @

0.1N I

2

0 3 3 # f 2 : 0 0 9 3 9 #

2

S

2

O

3

0 4 9 6 @ = 0 3 9 #

V

1

X f

1

= V

2

X f

2

^; ⁼ ^D ^D ^> ⁰ ^< ³ ^#